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1

A review of Mg metal-promoted CF bond activation; a reliable synthetic approach to difluorinated organic compounds

Kenji Uneyama, Hideki Amii

Journal:

Journal of Fluorine Chemistry

Année:

2002

Langue:

english

Fichier:

PDF, 207 KB

english, 2002

2

Reactions of benzeneselenenyl fluoride generated by XeF2-(PhSe)2 system with electron-deficient alkenes

Kenji Uneyama, Shigemoto Hiraoka, Hideki Amii

Journal:

Journal of Fluorine Chemistry

Année:

2000

Langue:

english

Fichier:

PDF, 109 KB

english, 2000

3

A new finding in selective Baeyer–Villiger oxidation of α-fluorinated ketones; a new and practical route for the synthesis of α-fluorinated esters

Satoru Kobayashi, Hiroaki Tanaka, Hideki Amii, Kenji Uneyama

Journal:

Année:

2003

Langue:

english

Fichier:

PDF, 232 KB

english, 2003

4

A facile synthesis of difluoromethylaziridines

Masayuki Mae, Makoto Matsuura, Hideki Amii, Kenji Uneyama

Journal:

Tetrahedron Letters

Année:

2002

Langue:

english

Fichier:

PDF, 87 KB

english, 2002

5

A new sequential defluorination route to α-fluoro-α,β-unsaturated ketones from trifluoromethyl ketones

Hiroshi Hata, Takeshi Kobayashi, Hideki Amii, Kenji Uneyama, John T. Welch

Journal:

Tetrahedron Letters

Année:

2002

Langue:

english

Fichier:

PDF, 284 KB

english, 2002

6

A rich chemistry of fluorinated imidoyl halides

Kenji Uneyama, Hideki Amii, Toshimasa Katagiri, Takeshi Kobayashi, Tsuyosi Hosokawa

Journal:

Journal of Fluorine Chemistry

Année:

2005

Langue:

english

Fichier:

PDF, 509 KB

english, 2005

7

Synthesis of 3,3,4,4-tetrafluoro-1,2-bis(imino)cyclobutanes: A cyclic version of fluorinated α-diimines

Hideki Amii, Mitsuhiro Kohda, Toshimasa Katagiri, Kenji Uneyama

Journal:

Journal of Fluorine Chemistry

Année:

2006

Langue:

english

Fichier:

PDF, 280 KB

english, 2006

8

α-Trifluoromethylated Carbanion Synthons

Uneyama, Kenji, Katagiri, Toshimasa, Amii, Hideki

Journal:

Accounts of Chemical Research

Année:

2008

Langue:

english

Fichier:

PDF, 592 KB

english, 2008

9

C−F Bond Activation in Organic Synthesis

Amii, Hideki, Uneyama, Kenji

Journal:

Chemical Reviews

Année:

2009

Langue:

english

Fichier:

PDF, 7.82 MB

english, 2009

10

Rh(I)-Catalyzed Coupling Cyclization of N -Aryl Trifluoroacetimidoyl Chlorides with Alkynes: One-Pot Synthesis of Fluorinated Quinolines

Amii, Hideki, Kishikawa, Yosuke, Uneyama, Kenji

Journal:

Organic Letters

Année:

2001

Langue:

english

Fichier:

PDF, 63 KB

english, 2001

11

Rhodium(I)-Catalyzed Successive Double Cleavage of Carbon−Carbon Bonds of Strained Spiro Cyclobutanones

Murakami, Masahiro, Takahashi, Kunio, Amii, Hideki, Ito, Yoshihiko

Journal:

Journal of the American Chemical Society

Année:

1997

Langue:

english

Fichier:

PDF, 66 KB

english, 1997

12

Formation and structure of a fluorinated [2.2]paracyclophan-1-ene

Amii, Hideki, Hayashi, Ryotaro, Seo, Motoharu, Katahira, Yukako, Kobayashi, Akira, Uneyama, Kenji

Journal:

Journal of Fluorine Chemistry

Année:

2013

Langue:

english

Fichier:

PDF, 648 KB

english, 2013

13

Nucleophilic fluoroalkylation/cyclization route to fluorinated phthalides

Inaba, Masanori, Sakai, Tatsuya, Shinada, Shun, Sugiishi, Tsuyuka, Nishina, Yuta, Shibata, Norio, Amii, Hideki

Journal:

Beilstein Journal of Organic Chemistry

Année:

2018

Langue:

english

Fichier:

PDF, 307 KB

english, 2018

14

Computer-Aided Design of Postpolymerization Modification Reaction Based on Aminolysis of Î±,Î±-Difluoroacetate Esters

Kakuchi, Ryohei, Fukasawa, Kota, Kikuchi, Moriya, Narumi, Atsushi, Kawaguchi, Seigou, Li, Yao, Kim, Hyung, Amii, Hideki

Journal:

Année:

2020

Fichier:

PDF, 3.62 MB

2020

15

Copper-Catalyzed Aromatic Trifluoromethylation via Group Transfer from Fluoral Derivatives

Hideaki Kondo, Masahiro Oishi, Kenichi Fujikawa, Hideki Amii

Journal:

Advanced Synthesis & Catalysis

Année:

2011

Langue:

english

Fichier:

PDF, 279 KB

english, 2011

16

Bemerkenswerter Einfluß von Silylsubstituenten auf den elektrocyclischen Ringschluß von Vinylallenen

Prof. Masahiro Murakami, Hideki Amii, Kenichiro Itami, Prof. Yoshihiko Ito

Journal:

Angewandte Chemie

Année:

1995

Fichier:

PDF, 222 KB

1995

17

σ-Bond Stretching: A Static Approach for a Dynamic Process

David Scheschkewitz, Hideki Amii, Heinz Gornitzka, Wolfgang W. Schoeller, Didier Bourissou, Guy Bertrand

Journal:

Angewandte Chemie

Année:

2004

Langue:

english

Fichier:

PDF, 137 KB

english, 2004

18

Titelbild: σ-Bond Stretching: A Static Approach for a Dynamic Process (Angew. Chem. 5/2004)

David Scheschkewitz, Hideki Amii, Heinz Gornitzka, Wolfgang W. Schoeller, Didier Bourissou, Guy Bertrand

Journal:

Angewandte Chemie

Année:

2004

Fichier:

PDF, 21 KB

2004

19

A Remarkable Effect of Silyl Substitution on Electrocyclization of Vinylallenes

Prof. Masahiro Murakami, Hideki Amii, Kenichiro Itami, Prof. Yoshihiko Ito

Journal:

Angewandte Chemie International Edition

Année:

1995

Langue:

english

Fichier:

PDF, 207 KB

english, 1995

20

σ-Bond Stretching: A Static Approach for a Dynamic Process

David Scheschkewitz, Hideki Amii, Heinz Gornitzka, Wolfgang W. Schoeller, Didier Bourissou, Guy Bertrand

Journal:

Angewandte Chemie International Edition

Année:

2004

Langue:

english

Fichier:

PDF, 137 KB

english, 2004

21

Cover Picture: σ-Bond Stretching: A Static Approach for a Dynamic Process (Angew. Chem. Int. Ed. 5/2004)

David Scheschkewitz, Hideki Amii, Heinz Gornitzka, Wolfgang W. Schoeller, Didier Bourissou, Guy Bertrand

Journal:

Angewandte Chemie International Edition

Année:

2004

Fichier:

PDF, 21 KB

2004

22

ChemInform Abstract: Mg0-Promoted Selective C—F Bond Cleavage of Trifluoromethyl Ketones: A Convenient Method for the Synthesis of 2,2-Difluoro Enol Silanes.

Hideki Amii, Takeshi Kobayashi, Yasushi Hatamoto, Kenji Uneyama

Journal:

Année:

1999

Fichier:

PDF, 31 KB

1999

23

ChemInform Abstract: Reactions of Benzeneselenenyl Fluoride Generated by XeF2—(PhSe)2 System with Electron-Deficient Alkenes.

Kenji Uneyama, Shigemoto Hiraoka, Hideki Amii

Journal:

Année:

2000

Fichier:

PDF, 36 KB

2000

24

ChemInform Abstract: Palladium-Catalyzed tert-Butoxycarbonylation of Trifluoroacetimidoyl Iodides.

Hideki Amii, Yosuke Kishikawa, Katsuhiko Kageyama, Kenji Uneyama

Journal:

Année:

2000

Fichier:

PDF, 30 KB

2000

25

ChemInform Abstract: First Synthesis of 3,3-Difluoroserine and Cysteine Derivatives via Mg(0)-Promoted Selective C—F Bond Cleavage of Trifluoromethylimines.

Masayuki Mae, Hideki Amii, Kenji Uneyama

Journal:

Année:

2000

Fichier:

PDF, 30 KB

2000

26

ChemInform Abstract: A Novel Intramolecular Defluorinative Cyclization Approach to the Synthesis of Difluoromethylated Quinazolic Acid Derivatives.

Jian Hao, Hironari Ohkura, Hideki Amii, Kenji Uneyama

Journal:

Année:

2001

Fichier:

PDF, 28 KB

2001

27

ChemInform Abstract: A Practical and Highly Efficient Synthesis of α-(Trimethylsilyl)-difluoroacetates.

Hideki Amii, Takeshi Kobayashi, Kenji Uneyama

Journal:

Année:

2001

Fichier:

PDF, 28 KB

2001

28

ChemInform Abstract: Preparation and Thermal Behavior of 3,3,4,4-Tetrafluorocyclobutane-1,2-diols: A New Family of Cyclobutane-1,2-diols.

Satoru Kobayashi, Youko Yamamoto, Hideki Amii, Kenji Uneyama

Journal:

Année:

2001

Fichier:

PDF, 30 KB

2001

29

ChemInform Abstract: Pd-Catalyzed Asymmetric Hydrogenation of α-Fluorinated Iminoesters in Fluorinated Alcohol: A New and Catalytic Enantioselective Synthesis of Fluoro α-Amino Acid Derivatives.

Hajime Abe, Hideki Amii, Kenji Uneyama

Journal:

Année:

2001

Fichier:

PDF, 36 KB

2001

30

ChemInform Abstract: A Trial Toward the Synthesis of γ-Fluorinated β-Amino-α-thiohydroxyamino Acid: A Finding of Desulfurizative C—C Bond Formation in Thio-Wittig-Type Rearrangement of S-(N-Aryl-trifluoroacetimidoyl)thioglycolates.

Kenji Uneyama, Hironari Ohkura, Jian Hao, Hideki Amii

Journal:

Année:

2001

Fichier:

PDF, 39 KB

2001

31

ChemInform Abstract: Rh(I)-Catalyzed Coupling Cyclization of N-Aryl Trifluoroacetimidoyl Chlorides with Alkynes: One-Pot Synthesis of Fluorinated Quinolines.

Hideki Amii, Yosuke Kishikawa, Kenji Uneyama

Journal:

Année:

2001

Fichier:

PDF, 38 KB

2001

32

ChemInform Abstract: Difluorinated Danishefsky′s Diene: A Versatile C4 Building Block for the Fluorinated Six-Membered Rings.

Hideki Amii, Takeshi Kobayashi, Hiroshi Terasawa, Kenji Uneyama

Journal:

Année:

2002

Langue:

english

Fichier:

PDF, 36 KB

english, 2002

33

ChemInform Abstract: A Facile Synthesis of Difluoromethylaziridines.

Masayuki Mae, Makoto Matsuura, Hideki Amii, Kenji Uneyama

Journal:

Année:

2002

Fichier:

PDF, 29 KB

2002

34

ChemInform Abstract: A Review of Mg Metal-Promoted C—F Bond Activation; a Reliable Synthetic Approach to Difluorinated Organic Compounds

Kenji Uneyama, Hideki Amii

Journal:

Année:

2002

Fichier:

PDF, 25 KB

2002

35

A New Sequential Defluorination Route to α-Fluoro-α,β-Unsaturated Ketones from Trifluoromethyl Ketones.

Hiroshi Hata, Takeshi Kobayashi, Hideki Amii, Kenji Uneyama, John T. Welch

Journal:

Année:

2002

Fichier:

PDF, 32 KB

2002

36

New Approaches to Stereoselective Synthesis of Fluorinated Amino Acids

Kenji Uneyama, Toshimasa Katagiri, Hideki Amii

Journal:

Année:

2003

Fichier:

PDF, 74 KB

2003

37

A New Finding in Selective Baeyer—Villiger Oxidation of α-Fluorinated Ketones: A New and Practical Route for the Synthesis of α-Fluorinated Esters.

Satoru Kobayashi, Hiroaki Tanaka, Hideki Amii, Kenji Uneyama

Journal:

Année:

2003

Fichier:

PDF, 151 KB

2003

38

A Novel Route to the Fluorinated Diimines: Carbon Monoxide-Promoted Reductive Homocoupling of Fluorinated Imidoyl Iodides in the Presence of a Palladium Catalyst.

Hideki Amii, Mitsuhiro Kohda, Motoharu Seo, Kenji Uneyama

Journal:

Année:

2003

Fichier:

PDF, 80 KB

2003

39

Unusual Reactions of N-Allylic Difluoroenamines under Thermal Conditions.

Hideki Amii, Yutaka Ichihara, Takashi Nakagawa, Takeshi Kobayashi, Kenji Uneyama

Journal:

Année:

2004

Fichier:

PDF, 104 KB

2004

40

Mg-Promoted Double Silylation of Trifluoroacetimidoyl Chlorides. A New Entry to the Fluorinated Dianion Equivalents.

Takeshi Kobayashi, Takashi Nakagawa, Hideki Amii, Kenji Uneyama

Journal:

Année:

2004

Fichier:

PDF, 148 KB

2004

41

Oxidative Cross-Coupling of β,β-Difluoroenol Silyl Ethers with Nucleophiles: A Dipole-Inversion Method to Difluoroketones.

Kenji Uneyama, Hiroaki Tanaka, Satoru Kobayashi, Manabu Shioyama, Hideki Amii

Journal:

Année:

2004

Fichier:

PDF, 23 KB

2004

42

Catalytic Route to the Synthesis of Optically Active β,β-Difluoroglutamic Acid and β,β-Difluoroproline Derivatives.

Atsushi Suzuki, Masayuki Mae, Hideki Amii, Kenji Uneyama

Journal:

Année:

2004

Fichier:

PDF, 30 KB

2004

43

A Rich Chemistry of Fluorinated Imidoyl Halides

Kenji Uneyama, Hideki Amii, Toshimasa Katagiri, Takeshi Kobayashi, Tsuyosi Hosokawa

Journal:

Année:

2005

Fichier:

PDF, 8 KB

2005

44

The Catalytic Version of Stoichiometric Organic Synthesis

Journal:

Année:

2005

Fichier:

PDF, 8 KB

2005

45

ChemInform Abstract: Aromatic Trifluoromethylation Catalytic in Copper.

Masahiro Oishi, Hideaki Kondo, Hideki Amii

Journal:

Année:

2009

Fichier:

PDF, 19 KB

2009

46

ChemInform Abstract: C—F Bond Activation in Organic Synthesis

Hideki Amii, Kenji Uneyama

Journal:

Année:

2009

Fichier:

PDF, 11 KB

2009

47

ChemInform Abstract: Sodium Bromodifluoroacetate: A Difluorocarbene Source for the Synthesis of gem-Difluorocyclopropanes.

Kojun Oshiro, Yoshimichi Morimoto, Hideki Amii

Journal:

Année:

2010

Fichier:

PDF, 24 KB

2010

48

ChemInform Abstract: Novel Axially Chiral Phosphine Ligand with a Fluoro Alcohol Moiety for Rh-Catalyzed Asymmetric Arylation of Aromatic Aldehydes.

Satoshi Morikawa, Kyosuke Michigami, Hideki Amii

Journal:

Année:

2010

Fichier:

PDF, 28 KB

2010

49

ChemInform Abstract: Copper-Catalyzed Aromatic Trifluoromethylation via Group Transfer from Fluoral Derivatives.

Hideaki Kondo, Masahiro Oishi, Kenichi Fujikawa, Hideki Amii

Journal:

Année:

2011

Fichier:

PDF, 29 KB

2011

50

ChemInform Abstract: A New Method for Aromatic Difluoromethylation: Copper-Catalyzed Cross-Coupling and Decarboxylation Sequence from Aryl Iodides.

Kenichi Fujikawa, Yasutaka Fujioka, Akira Kobayashi, Hideki Amii

Journal:

Année:

2012

Fichier:

PDF, 30 KB

2012